Adsorption of Cu (II), Zn (II) and Ni (II) ions from aqueous solution by date stones

S. Khenchelaoui, A. Gherbia, Y. Medkour, A. Chergui, A. R. Yeddou, R. Kerbachi

Abstract


Abstract: The present study is concerned with the valorization of date stones for the waste water treatment. Date stones as adsorbent were characterized by X-ray diffraction, FT-IR and SEM, than tested for the adsorption of Cu (II), Zn (II) and Ni (II) from aqueous solotion. The effects of different parameters on the adsorption of metal metals such as the contact time, the initial concentration and the pH of the solution were investigated. The adsorption capacity was highest at pH5. Cu (II) had higher adsorption capacity than Zn (II) and Ni (II). The equilibrium data were fitted using Freundlich and Langmuir isotherm models.


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Bouhamed, F.; Elouer, Z.; Bouzid, J.Adsorptive removal of copper (II) from aqueous solutions on activated carbon prepared from Tunisian date stones: Equilibrium, kinetics and thermodynamics, Taiwan institute of chemical Engineers 43 (2012) 741-749.

Kocaoba, S.; Orhan, Y.; Akyüz,T. Kinetics and equilibrium studies of heavy metal ions removal by use of natural zeolite, Desalination214 (2007) 1-10.

Chatterjee, S.K.; Bhattacharjee, I.; G. Chandra. Biosorption of heavy metals from industrial wastewater by Geobacillusthermodenitrificans, Journal of Hazardous Materials 175 (2010) 117-125.

Y.Y. Pei, J.Y. Liu.Adsorption of Pb2+ in wastewater using adsorbent derived from grape fruit peel, Advanced Material Research, 391–392 (2011) 968-972.

Pillai, M.G. ; Simha, P. ; Gugalia, A. Recovering urea from human urine by bio-sorption onto microwave activated carbonized coconut shells: equilibrium, kinetics, optimization and field studies, Journal of Environmental Chemical Engineering 2 (1) (2014) 46-55.

Tseng, R-L.; Wu, F.-C. ; Juang,R.-S. Liquid-phase adsorption of dyes and phenols using pine wood-based activated carbons, Carbon 41 (2003) 487-495.

Liang, S. ; Guo, X. ; Tian, Q. Adsorption of Pb2+ and Zn2+ from aqueous solutions by sulfured orange peel,Desalination, 275 (2011) 212-216.

Basu, M.; Guha, A.K.; Ray, L. Biosorptive removal of lead by lentil husk, Journal of Environmental Chemical Engineering 3 (2) (2015) 1088-1095.

Aman, T. ; Kazi, A.A. ; Sabri, M.U. ; Bano, Q. Potato peels as solid waste for the removal of heavy

metal copper (II) from waste water/industrial effluent Colloids Surf, Biointerfaces 63 (2008) 116-121.

Namasivayam, C.; Radhika, R.; Suba, S. Uptake of dyes by a promising locally available agricultural solid waste: coir pith, Waste Management 21 (2001) 381-387.

Anwar, J.; Shafique, U.; Waheeduz, Z.; Salman, M.; Dar, A.; Anwar, S. Removal of Pb(II) and Cd(II) from water by adsorption on peels of banana,Bioresource Technology 101 (2010) 1752-1755.

Aygun, A.; Yenisoy-Karakas, S.; Duman I. Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties,Microporous Mesoporous Materials 66 (2003) 189-195.

Iqbal, M.; Saeed, A.; Kalim, I. Characterization of adsorptive capacity and investigation of mechanism of Cu2 +, Ni2 + and Zn2 + adsorption on mango peel waste from constituted metal solution and genuine electroplating effluent, Separation Science and Technology 44 (2009) 3770-3791.

Tsai, W.T.; Chang, C.Y.; Lin, M.C.; Chien, S.F.; Sun, H.F.; Hsieh, M.F . Adsorption of acid dye onto activated carbons prepared from agricultural waste bagasse by ZnCl2 activation, Chemosphere 45 (2001) 51-58.

Arami, M. ; Limaee, N.Y.; Mahmoodi, N.M.; Tabrizi, N.S. Equilibrium and kinetics studies for the adsorption of direct and acid dyes from aqueous solution by soy meal hull,Journal of Hazardous Materials 135 (2006)171-179.

Aygun, A.; Yenisoy-Karakas, S.; Duman, I. Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties,Microporous and Mesoporous Materials 66 (2003)189-195.

Fiol, N. ; Villaescusa, I. ; Martínez, M. ; Miralles, N. ; Poch, J. ; Serarols, J. Sorption of Pb(II), Ni(II), Cu(II) and Cd(II) from aqueous solution by olive stone waste, Separation and Purification Technology 50 (2006) 132-140.

Zou, W.; Zhao, L.; Zhu, L. Efficient uranium (VI) biosorption on grapefruit peel: Kinetic study and thermodynamic parameters, Journal of Radioanalytical and Nuclear Chemistry 292 (2012)1303-1315.

Velazquez-Jimenez, L. H.; Pavlick, A. ; Rangel-Mendez, J. R. Chemical characterization of raw and treated agave bagasse and its potential as adsorbent of metal cations from water,Industrial Crops and Product journal 43 (2013)200-206.

Ghnimi, S.; Umer, S.; Karim, A.; Kamal-Eldin, A. Date fruit (Phoenix dactylifera L.): An underutilized food seeking industrial Valorization, NFS Journal6(2017)1–10.

Chandrasekaran, M. ; Bahkali, A. H. Valorization of date palm (Phoenix dactylifera) fruit processing by-products and wastes using bioprocess technology – Review, Saudi Journal of Biological Sciences20(2013) 105–120.

Sentorun-Shalaby, C.; Ucak-Astralioglu, M.G.; Artok, L.; Sarici, C. Preparation and characterization of activated carbons by one-step steam pyrolysis/activation from apricot stones, Microporous and Mesoporous Materials 88 (2006) 126-134.

Tongpoothorn,W.; Sriuttha, M.; Homchan, P.; Chanthai, S.; Ruangviriyachai, C. Preparation of activated carbon derived from Jatrophacurcas fruit shell by simple thermo-chemical activation and characterization of their physicochemical properties, Chemical Engineering Research and Design 89 (2011) 335-340.

Hadouna, H. ; Sadaoui, Z. ; Souami, N. ; Sahel, D. ; Toumert, I. Characterization of mesoporous carbon prepared from date stems by H3PO4 chemical activation, Applied Surface Science 280 (2013) 1-7.

Danish, M.; Hashim, R.; Mohamed Ibrahim, M.N.; Sulaiman, O. Optimized preparation for large surface area activated carbon from date (Peonixdactylifera L.) stone biomass, Biomass and Bioenergy 61 (2014) 167-178.

Sun, X.F.; XU, F.; Sun, R.C.;Fowler, P.; Baird,M.S. Characteristics of degraded cellulose obtained from steam-exploded wheat straw, Carbohydrate Research 340 (2005) 97-106.

Pavan, F.A.; Lima, E.C.; Silvio Dias, L.P.; Ana Mazzocato, C. Methylene blue biosorption from aqueous solution by yellow passion fruit waste, Journal of Hazardous Materials 150 (2008) 703-712.

Bouchelta, C. ; Medjram, M.S. ; Bertrand, O. ; Bellat, J.P. Preparation and characterization of activated carbon from date stones by physical activation with steam, Journal of Analyticaland Applied Pyrolysis 82 (2008) 70-77.

Foo,K.Y.; Hameed,B.H. Preparation and characterization of activated carbon from pistachio nut sells via microwave-induced chemical activation, Biomass and BioEnergy35 (2011) 3257-3361.

Hu, H. ; Zhang, J. ; Lu, K. ; Tian, Y. Characterization of Acidosaraedulis shoot shell and its biosorption of copper ions from aqueous solution, Journal of Environmental Chemical Engineering3 (2015) 357-364.

Amarasinghe, B.M.W.P.K..; Williams, R.A. Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater, Chemical Engineering Journal 132 (2007) 299-309.

Luo, F. ; Liu, Y. ; Li, X. ; Xuan, Z. ; Ma, J. Biosorption of lead ion by chemically-modifies biomass of marine brown algae Laminaria Japonica, Chemosphere 64 (2006) 1122-1127.

Guan, Y. T.; Wang, S. H.; Wang, M. H.; Hou, Z. X.; Hu, X. D.; Wang, H.;Zhang, N. Effect of Initial Concentration of Cu2+ on the adsorption performance of hydroxyapatite, Advanced Materials Research 98 (2014) 312-315.

Melichova, Z.; Hromada, L. Adsorption of Pb2+ and Cu2+ions from aqueous solutions on natural bentonite, Polish Journal of Environment Studies 22, 2 (2013) 457-464.

Rahman, M. S.; Sathasivam, K. V. Heavy metal adsorption onto Kappaphycus sp. from aqueous solutions: the use of error functions for validation of isotherm and kinetics models, BioMed Research International (2015) 1-13.

Ciftci, T. D. Adsorption of Cu(II) on three adsorbents, Fe3O4/Ni/NixBnanocomposite, carob (Ceratoniasiliqua), and grape seeds: a comparative study, Turkish Journal Chemistry 41 (2017) 760 -772.

Cay, S.; Uyanik, A.; Ozaji, A.Single and binary component adsorprtion of copper(II) and cadmium(II) from aqueous solutions using tea-industry waste, Separation and purification technology,38 (2004) 273-280.

Chuan, T.G.; Jumasiah, A.; Azni, I.; Katayon, S.; Thomas Choong, S.Y. Rice husk as a potentially low-cost bio-sorbent for heavy metal and dye removal: on overview,Desalination 175 (2005) 305-316.

Baccar, R.; Bouzid, J.; Feki, M.; Montiel, A. Preparation of activated carbon from Tunisian olive-waste cakes and its application for adsorption of heavy metal ions, Journal of Hazardous Materials 162 (2006) 1522-1529.

Kobya, M.; Demirbas, E.; Senturk, E.; Ince, M. Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone,Biosource Technology 96 (2005) 1518-1521.

Chu, K.H. Removal of copper from aqueous solution by chitosan in prawn shell: adsorption equilibrium and kinetics, Journal of Hazardous Materials B90 (2002) 77-95.

Mellah, A.; Chegrouch, S. The removal of zinc from aqueous solutions by natural Bentonite,Water Research 31 (1997) 621-629.

Mohan, D.; Singh, K.P. Single-and multi-component adsorption of cadmium and zinc using activated carbon derived from bagasse an agricultural waste, Water Research 36 (2002) 2304-2318.

Agrawal, A.; Sahu, K.K.; Pandey,B.D. Removal of zinc from aqueous solutions using sea nodule residue, Colloids and SurfacesA237 (2004) 133-140.

Bailey, S.E.; Olin, T.J.;Bricka, R.M.; Adrian, D.D. A review of potentially low-cost sorbents for heavy metals, Water Research33 (1999) 2469-2479.

Reddad, Z.; Gerente, C.; Andres, Y.; Cloire, L.P. Adsorption of several metal ions onto a low-cost biosorbent:kinetic and equilibrium studies, Environmental Science and Technology 36 (2002) 2067-2073.

Malkoc, E.; Nuhoglo,Y.Investigations of nickel (II) removal from aqueous solutions using tea factory waste, Journal of Hazardous MaterialsB127 (2005) 120-128.

Ho, Y.S.; John Wase, D.A.; Forster, C.F. Batch Nickel removal from aqueous solution by spharagnum moss peat, Water Research 29 (1995) 1327-1332.

Okieimen, F.E.; Onyenkpa, V.H. Removal of heavy metal ions from aqueous solutions with melon (Citrullus vulgaris) Seed Husks, Biological Wastes 29 (1989) 11-16.

Raoa, M.; Parawate, A.V.; Bhole, A.G. Removal of Cr6+ and Ni2+ from aqueous solution using bagasse and fly ash, Waste Management22 (2002) 821-830.


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