Organic-inorganic hybrid zeolite silica materials by grafting of trimethylchlorosilane TMCS: part I: preparation and characterization

O. Bouchher, K. Benrachedi, M. Makhlouf, S. M. Messabih, K. Louhab

Abstract


Abstract: The functionalization of our 13X zeolite was carried out by the post-synthesis method using an organosilane of the Trimethylchlorosilane type (TMCS) to obtain a more hydrophobic organic-inorganic hybrid zeolite. Our zeolite before and after grafting was characterized by different analysis techniques (XRD, FTIR, BET, and SEM). The XRD results of the grafted 13X zeolite, show that the functionalization does not destroy the crystal structure of the material. FT-IR analysis of the 13X zeolite before and after grafting confirms the grafting of our organosilane on the surface by the disappearance of the absorption band of the silanol groups at 980 cm-1 and the appearance of a band of absorption attributed to the vibrations of the trimethylsilyl Si (CH3) group at 2970 cm-1. The specific surface area of our grafted 13X has been reduced by 63.22 m2 / g thanks to the organic group which has been grafted on the external surface. According to SEM results, the morphology of the surface of our material was slightly modified after grafting. The results of various analyses demonstrated that the grafted 13X zeolite is successfully obtained using the post-synthesis method.


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References


Moshoeshoe, M.; Nadiye-Tabbiruka, M. S.; Obuseng, V. Review of the Chemistry, Structure, Properties and Applications of Zeolites. American Journal of Materials Science 7 (5) (2017) 196-221

Rahman, M. M.; Hasnida, N.; Nik, W. W. Preparation of Zeolite Y Using Local Raw Material Rice Husk as a Silica Source. Journal of Scientific Research 1 (2) (2009) 285-291

Rao, G.P.C.; Satyaveni, S.; Ramesh, A.; Seshaiah, K.; Murthy, K.S.N.; Choudary, N.V. Sorption of cadmium and zinc from aqueous solutions by zeolite 4A, zeolite 13X and bentonite. J. Environ. Manage 81 (2006) 265–272.

Deer, W. A.; Howie, R. A.; Wise, W. S.; Zussmann, J. Rock-forming minerals Volume 4B. Framework silicates: Silica minerals, Feldspathoids and the Zeolites.Geological Magazine 143 (4) (2004) 557-557

Stocker, K.; Ellersdorfer, M.; Lehner, M.; Raith, J. G. Characterization and Utilization of Natural Zeolites in Technical Applications. BHM Berg-und Hüttenmännische Monatshefte 162 (4) (2017) 142-147.

Hovhannisyan, V. A.; Dong, C. Y.; Lai, F. J.; Chang, N. S. ; Chen, S. J. Natural zeolite for adsorbing and release of functional materials. Journal of Biomedical Optics 23(9) (2018) 091411

Bennett, G. F.; Yang, R. T. Adsorbents: fundamentals and applications. Journal of Hazardous Materials, 1(109) (2004) 227-228.

Ennaert, T.; Van Aelst, J.; Dijkmans, J.; De Clercq, R.; Schutyser, W.; Dusselier, M.; Sels, B. F. Potential and challenges of zeolite chemistry in the catalytic conversion of biomass. Chemical Society Reviews 45 (3) (2016) 584–611

Zhang, L.; Chen, K.; Chen, B.; White, J. L.; Resasco, D. E. Factors that determine zeolite stability in hot liquid water. Journal of the American Chemical Society 137(36) (2015) 11810–11819

Ratner, B. D.; Hoffman, A. S.; McAthur, S. L. Physicochemical Surface Modification of Materials Used in Medicine. Biomaterials Science (2020) 487–505

Sayari, A.; Hamoudi, S. Periodic mesoporous silica-based organic-inorganic nanocomposite materials. Chemistry of Materials 13(10) (2001) 3151–3168

Shang, F.; Wu, S.; Guan, J.; Sun, J.; Liu, H.; Wang, C.; Kan, Q. A Comparative study of aminopropyl-functionalized SBA-15 prepared by grafting in different solvents. Reaction Kinetics, Mechanisms and Catalysis 103(1) (2011) 181–190

Maria Chong, A. S.; Zhao, X. S. Functionalization of SBA-15 with APTES and characterization of functionalized materials. The Journal of Physical Chemistry B 107(46) (2003) 12650–12657.

Zhao, X. S.; Lu, G. Q. Modification of MCM-41 by Surface Silylation with Trimethylchlorosilane and Adsorption Study. The Journal of Physical Chemistry B 102 (9) (1998) 1556-1561

Byrappa, K.; Suresh Kumar, B.V. Characterization of Zeolite by Infrared Spectroscopy. Asian Journal of Chemistry 19 (6) (2007) 4933-4935.

Ma, Y.; Yan, C.; Alshameri, A.; Qiu, X.; Zhou, C. Synthesis and characterization of 13X zeolite from low-grade natural kaolin. Advanced Powder Technology 25 (2) (2014) 495–499

Zhao, X. S.; Lu, G. Q.; Hu, X. Characterization of the structural and surface properties of chemically modified MCM-41material. Microporous and Mesoporous Materials 41(1-3) (2000) 37 - 47

Sasikala, S.; Gopi, K. H.; Bhat, S. D. Sulfosusscinic acid-sulfonated polyether ether ketone/organo functionalized microporous zeolite-13X membrane electrolyte for direct methanol fuel cells. Microporous and Mesoporous Materials 236 (2016) 38-47.

Chen, D.; Hu, X.; Shi, L.; Cui, Q.; Wang, H.; Yao, H. Synthesis and characterization of zeolite X from lithium slag. Applied Clay Science 59 (2012) 148–151.

Zhan, B.Z.; White, M.A.; Lumsden, M.; Mueller-Neuhaus, J.; Robertson, K.N.; Cameron, T.S.; Gharghouri, M. Control of Particle Size and Surface Properties of Crystals of NaX Zeolite. Chemistry of Materials 14(9) (2002) 3636-3642.

Byrappa, K.; Kumar, B. S. Characterization of zeolites by infrared spectroscopy. Asian journal of chemistry 19(6) (2007) 4933 -4933

Meléndez-Ortiz, H. I.; Perera-Mercado, Y.; Mercado-Silva, J. A.; Olivares-Maldonado, Y.; Castruita, G.; García-Cerda, L. A. Functionalization with amine-containing organosilane of mesoporous silica MCM-41 and MCM-48 obtained at room temperature. Ceramics International 40(7) (2014) 9701–9707

Rongchapo, W.; Deekamwong, K.; Loiha, S.; Prayoonpokarach, S.; Wittayakun, J. Paraquat adsorption on NaX and Al-MCM-41. Water Science and Technology 71(9) (2015) 1347–1353.

Cheng, W. P.; Gao, W.; Cui, X.; Ma, J. H.; Li, R. F.Phenol adsorption equilibrium and kinetics on zeolite X/activated carbon composite. Journal of the Taiwan Institute of Chemical Engineers 62 (2016) 192-198

Barsotti, E.; P. Tan, S.; Saraji, S.; Piri, M.; Chen, J.H. A review on capillary condensation in nanoporous media: Implications for hydrocarbon recovery from tight reservoirs. Journal homepage,Fuel 184 (2016) 344 -361


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