Synthesis and characterization of nano-magnetic material based on (carbon nanotubes / nickel ferrite): Application for the removal of methyl orange dye from contaminated water

K. Seffah, N. Bensacia, A. Skender, E. Flahaut, A. Hadj-ziane-zafour

Abstract


Abstract: This work aims the synthesis of (DWNTCs / NiFe2O4) by refluxing process. Herein, the synthesized adsorbent was characterized via Fourrier Transform Infrared Spectroscopy (FTIR), X-ray diffraction (DRX), BET, zeta potential and transmission electron microscopy (TEM), where the adsorption of methyl orange on (DWNTCs / NiFe2O4) has been carried out by studying the adsorption kinetics, pH, mass and the initial concentration. The results indicated that the maximum adsorption rate is 7.77 mg.g-1 at pH 5 with 100 mg of (DWNTCs / NiFe2O4), and an initial orange methyl concentration of 10 mg.l-1. In addition, the adsorption process describes a second-order kinetic model, where the modeling of adsorption isotherms showed that the Freundlich one seem to be the adequat model describing the adsorption process with R2 = 0.97.

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References


Jain, R.; Sikarwar, S. Photocatalytic and adsorption studies on the removal of dye Congo red from wastewater. International Journal of Environment and Pollution 27(2006)158–178.

Sanghi, R.; Bhattacharya, B. Review on decolorisation of aqueous dye solutions by low cost adsorbents. Coloration Technology. 118 (5) (2002) 256–269.

Abraham, T. Economics of ceramic magnets. The American Ceramic Society 73 (1994) 62–65.

Iijima S., Helical microtubules of graphitic carbon. Nature. 354(1991)56-58.

Dai,L.M.; Mau, A.W.H. Controlled synthesis and modification of carbon nanotubes and C60: carbon nanostructures for advanced polymeric composite materials. Advanced Materials 13(2001)899-913.

Flahaut, E.; Bacsa, R.; Peigney, A. Gram-scale CCVD synthesis of double walled carbon nanotubes. Chemical Commun 12 (2003) 1442-3.

Bortolamiol, T.; Lukanov, P.; Galibert, A-M.; Soula, B.; Lonchambon, P.; Flahaut, E. Double-Walled Carbon Nanotubes: Quantitative purification assessment, balance between purification and degradation and solution filling as an evidence of opening. Carbon 78(2014)79-90.

Maaz, K.; Karim, S.; Mumtaz, A.; Hasanain,S.K.; Liu,J.; Duan, J.L. Synthesis and magnetic characterization of nickel ferrite nanoparticles prepared by co-precipitation route. Journal of Magnetism and Magnetic Materials.321 (2009), 1838–1842.

Nejati, K., Zabihi, R. Preparation and magnetic properties of nano size nickel ferrite particles using hydrothermal method. Chemistry Central Journal 6 (2012)23.

Senthilkumar, B., Kalai Selvan, R., Vinothbabu, P., Perelshtein, I., Gedanken, A. Structural, magnetic, electrical and electrochemical properties of NiFe2O4 synthesized by the molten salt technique. Materials Chemistry and Physics 130 (2011)285–292.

Lingamdinne, L.P.; Koduru J.R .Studies on removal of Pb(II) and Cr(III) using graphene oxide based inverse spinel nickel ferrite nano-composite as sorbent. Hydrometallurgy .165 (2015)64-72.

Verma, K.C.; Singh, V.P.; Ram M., Shah J., Kotnala R.K. Structural, microstructural and magnetic properties of NiFe2O4, CoFe2O4 and MnFe2O4 nanoferrite thin films, J. Magn. Magn. Mater. 323 (2011) 3271- 3275.

T. Peng, X. Zhang, H. Lv, L. Zan, Preparation of NiFe2O4 nanoparticles and its visible – light-driven photoactivity for hydrogen production, Catal.Commun. 28 (2012) 116 – 119.

A. Jitianu, T. Cacciaguerra, R. Benoit, S. Delpeux, F. Beguin,S. Bonnamy, Synthesis and characterization of carbon nanotubes –TiO2 nanocomposites, Carbon 42 (2004) 1147 – 1151.

Ahmed, D.S.; Haider, A.J.; Mohammad, M.R. Comparesion of functionalization of multi walled carbon nanotubes treated by oil olive and nitric acid and their characterization. Energy Procedia 36(2013)1111-1118.

Yu, CH.; Al-Saadi, A.; Shih, S.J.; Qiu, L. Immobilization of BSA on silica-coated magnetic iron oxide nanoparticle. Journal of Physical Chemistry C 113(2009) 537-543.

Ho,Y.S.; Mckay, G. Pseudo-second order model for sorption processes. Process Biochem. 34(1999)451-465.

[18] Bensacia, N., Fechete I., Moulay, S., Hulea, O., Boos, A., Garin, F. Kinetic and equilibrium studies of lead (II) adsorption from aqueous media by KIT-6 mesoporous silica functionalized with –COOH. Comptes Rendus Chimie. 17 (2014)869-880.

Bensacia, N.; Fechete, I.; Moulay, S.; Debbih-Boustila,S.; Boos, A.; Garin, F. Removal of cadmium (II) from aqueous media using COOH/TUD-1 mesoporous solid. Kinetic and thermodynamic studies. Environmental Engineering and Management Journal. 13(2014), 10, 2675-2686 .

Freundlich, H.M.F. Over the adsorption in solution. Journal of Physical Chemistry.57(1906) 385-470.

Langmuir, I. The constitution and fundamental properties of solids and liquids. Part I. Solids, Journal of American Chemical Society. 38 (1916) 2221-2295.

Temkin, M.I., Pyzhev, V. Kinetics of ammonia synthesis on promoted iron catalyst. Acta Physico- Chimica. 12(1940), 327–356.

Ding ,H.;Li ,X.; Wang, J.; Zhang, X . Adsorption of chlorophenols from aqueous solutions by pristine and surfacefunctionalized single-walled carbon nanotubes Journal of Environmental Sciences .43 (2016)187-98.

Moulay, S.; Bensacia, N. Removal of heavy metals by homolytically functionalized poly(acrylic acid) with hydroquinone. International Journal of Industrial Chemistry . 4(2016) 369–389.


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