Synthesis and Characterization of Algeria Organo clays used for Elimination of Phosphate Anions from Aqueous Solution

S. Bandou, M. Amrani, O. Bouras


Abstract:. This study is based on synthesis and characterization of  three different clays (Sodic-bentonite noted  , Dialyl Dimethyl Ammonium Chloride-bentonite noted  and bentonite intercalated by Hexadecyl Trimethyl Ammonium Bromide or  .These three clay complexes were characterized by both  diffraction   and Fluorescence Scanning Electron Microscopy , Fourier transform infrared spectroscopy ,textural measurements (  specific surface areas and porosities) and the cationic exchange capacity .

Corresponding obtained results confirm the good intercalation of the  by the two used surfactants at low concentrations (  for  and for ).

Obtained results give basal spacing values around   and   , respectively for verified two aims firstly: The originality of this research, secondly for minimized the production cost of the adsorbents.

Adsorption kinetic study of phosphate ions   on these three matrices was carried out using kinetic models of pseudo-first, pseudo-second-order and intraparticular diffusion. Results obtained at the studied conditions (room temperature  ), ( acidic medium ) show clearly the good validity of the pseudo-second-order model which gives a better correlation coefficient both, for    and    compared to that obtained by   The aim of this present study was to evaluate the feasibility of using chicken eggshells as low-cost biosorbentfor nickel(II) ions adsorption from aqueous solutions. In order to clarify the adsorption process, batch experiments were performed to study the effect of operating parameters such asbiosorbent dose (1-10 g/L), initial concentration of nickel ions (10-50 mg/L), contact time (5-120 min) and temperature (20-50 °C). To describe the adsorption equilibrium, the experimental data were analyzed by the Langmuir, Freundlich and Temkin isotherm models. The Freundlich model showed better representation of data (R2> 0.999).The maximum adsorption capacity Adsorption isotherms give adsorbed amounts of about  and     onto      complexes, respectively, and for  as reference adsorbent. These results indicated the adsorption of phosphate anions   by the two prepared Algerian modified organo clays through interactions by the chemisorptions on the surface sites of each used modified clay complexes.

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Némery Garnier, J. The fate of phosphorus Nature Geoscience, 9 (2016) 343-344.

Levlin, E.; Hultman, B. Phosphorus recovery from phosphate rich Side streams in wastewater treatments. Proceedings of a Polish-Swedish seminar, Report:No10., Joint Polish-Swedish Reports, Gdansk Poland (2003).

Gullet, B.; Mc Lelland, J.; Padgett, D. System-wide planning for phosphorus reduction at Charlotte’s three largest waste water treatment plants. Proceedings of South Carolina. Environmental Conference, Columbia, 2003.

Yousef, L.; Achour, S. Elimination of the phosphate by physico-chemical processes. LARHYSS Journal, ISSN: 1112-3680,4(2005)129-140.

Lee, S. E.; Kim, K.S.; Ahn, J.H.; Kim, C.W. Comparison of phosphorus removal Characteristics between various biological nutrient removal processes. At SciTech. 36 (12) (1997) 61-68.

Smolders, G.J.F.; Van Loos drecht, M.C.M.; Heijnen, J.J. Teady-state Analysis to evaluate the phosphate removal capacity and acetate requirement of biological phosphorus removing main stream and side stream process configurations, Wat. Res 30 (11) (1996)2748-2760.

Wild, D.; Kisliakova, A.; Siegrist, H. P-fixation by Mg, Ca and zeolite during stabilization of excess sludge from enhanced biological P-removal .Wat. Sci. Tech. 31 (1-2) (1996) 391-398.

Matsch, L.C.; Drnevich, R.F. Biological nutrient removal in Advances in Water and Waste Treatment,Ann. Arbor. Sci. (1987).

Donnert, D.; Salecker, M.; Donnert, D.; Salecker, M. Elimination of phosphorus from municipal and industrial waste water. Wat. Sci. Tech . 40 (4-5) (1999) 195-202.

Brattebø, H.; Edward, H. Phosphorus removal by granular activated aluminum,Wat.Res. 20 (8) (1986) 977-986.

Hano,T.; Takanashi, H .; Hirata, M .; Urano, K .; Shunji . Removal of phosphorus from waste water by activated alumina adsorbent .Wat. Sci. Tech . 35 (7) (1997)39-46.

Mao-Xu, Zhu.; Kui-Ying, Ding.; Shao-Hui, Xu.; Xin, Jiang. Adsorption of phosphate on hydroxyaluminum and hydroxyiron –montmorillonite complexes, Journal of Hazardous Materials 165 (2009) 645-651.

Zamparas, Miltiadis.; Areti, Gianni.; Stathi, Panagiota.; Deligiannakis, Yiannis.; Zacharias, Ierotheos. Removal of phosphate from natural waters usin g innovative modified bentonites. J. Applied Clay Science ,( 2012)101–106.

Tanyol, Mehtap.; Yonten, Vahap.; Demir, Veyse. Removal of phosphate from aqueous solutions by chemical –and thermal-modified bentonite clay. J.Water .Air & Soil Pollution. Springer Link. (2015) 1-10.

Ahmad, M.B.; Hoidy,W. H.; Ibrahim, N.A.B.; Al-Mulla ,E.A.J. Modification of montmorillonite by new surfactants. J. Eng. Appl. Sci . 4 (3)(2009) 184-188.

Bouberka ,Z.; .Kacha ,S.; Kameche, M.; Elmaleh, S.; Derriche ,Z. Sorption study of aqueous solutions using modified clays. Journal of Hazardous Materials. B.119 (2005)117-124.

Bardon, C. Recommendations for the experimental determination of the capacity of exchange of the cations of the argillaceous mediums.(1983) Review IFP 38.

Lin, Y. The Criteria Analysis Methods of Wastewater [M]. Beijing. The Environmental Science Publishing House of China (2002) 332−334.

Makhokhi. Modification of the raw bentonite by several organic salts–applications for oils décoloration and adsorption of textiles dyes. (2008), phd disso, university of Telemcen.

Bouras,O. Adsorbent decked clay properties organophiles.Synthesis and Characterization. (2003), phd disso,university of Blida.

Su, J.; Huai–Guo, Huang.; Xiao-Ying, Jin .; Xiao, Lu.; Zu-Liang, Chen. Synthesis characterization and kinetic of surfactant-modified bentonite used to remove As(III) and As(V) from aqueous solution, Journal of Hazardous Materials . 185 (2011) 63-70.

Zaghouane. Boudiaf, Hassina. Préparation et caractérisation de matériaux à base d’argile algérienne. Application à l’adsorption de polluants organiques, Thèse de doctorat en Génie Chimique. Université de Ferhat Abbas Sétif. (2011).

Önal , M .,and Sarikaya , Y.Preparation and Characterization of Acid-Activated Bentonite Powders,Powder Technology. 172 (2007)14-18.

Olad, A.; Rashidzadeh, A. Preparation and anticorrosive properties of PANI/Na-MMT and PANI/O-MMT nanocomposites . Prog .Org. Coat . 62 (2008) 293-298.

Ho,Y.S. and G.McKay, Pseudo-Second Order Model for Sorption Processes, Process Biochemistry 34 (1999) 451-465.

Gammoudi , S.; Frini-Srasra, N.; Srasra , E. Influence of exchangeable cation of smectite on HDTMA adsorption Equilibrium, kinetic and thermodynamic studies. Applied Clay Science (2012) 69-99.

Zatta , Leandro .; Ramos Luiz , Pereira.; Wypych,Fernando. Acid-activated montmorillonite as heterogeneous catalysts for the esterification of lauric acid with methanol. Applied Clay Science 80 (2013)236.

Daimei,Chen.;Jian ,Chen.; Xinlong,Luan .; Haipeng, Ji.; Xia , Zhiguo. Characterization of anion–cationic surfactants modified montmorillonite and its application for the removal of methyl orange. Chemical Engineering Journal. 171 (2011) 1150 – 1158.

Lopeza ,D. G.; Gobernado-Mitre, I.; Fernandez ,J. F.; Merino J. C.; Pastor J. M.; Polymer . 46(2005) 2758–2765.

Kundu, S. and Gupta, A.K.Arsenic Adsorption onto Iron Oxide-Coated Cement (IOCC): Regression Analysis of Equilibrium Data with Several Isotherm Models and Their Optimization. Chemical Engineering Journal, 122 (2006)93-106.

Yusof ,A M .; Keat , L K .; Ibrahim, Z. Kinetic and Equilibrium Studies of the removal of ammonium ions from aqueous solution by rice husk ash –Synthesized zeolite Y and powdered and granulated forms of modernite .Journal of Hazardous Materials, 174 (1-3) (2010) 380-385.


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